Single Droplet Pattern in the Cylindrical Phase of Diblock Copolymer Morphology

نویسندگان

  • X. Ren
  • Juncheng Wei
چکیده

The Ohta-Kawasaki density functional theory of diblock copolymers gives rise to a nonlocal free boundary problem. Under a proper condition between the block composition fraction and the nonlocal interaction parameter, a pattern of a single droplet is proved to exist in a general planar domain. A smaller parameter range is identified where the droplet solution is stable. The droplet is a set which is close to a round disc. The boundary of the droplet satisfies an equation that involves the curvature of the boundary and a quantity that depends nonlocally on the whole pattern. The location of the droplet is determined by the regular part of a Green’s function of the domain. This droplet pattern describes one cylinder in space in the cylindrical phase of diblock copolymer morphology.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Many droplet pattern in the cylindrical phase of diblock copolymer morphology

The Ohta-Kawasaki density functional theory of diblock copolymers gives rise to a nonlocal free boundary problem. In a proper range of the block composition parameter and the nonlocal interaction parameter, an equilibrium pattern of many droplets exists in a general planar domain. A sub-range of the parameters is identified where the multiple droplet pattern is stable. This stable droplet patte...

متن کامل

Ring pattern solutions of a free boundary problem in diblock copolymer morphology

The cross section of a diblock copolymer in the cylindrical phase is made up of a large number of microdomains of small discs with high concentration of the minority monomers. Often several ring like microdomains appear among the discs. We show that a ring like structure may exist as a stable solution of a free boundary problem derived from the Ohta-Kawasaki theory of diblock copolymers. The ex...

متن کامل

Regulating block copolymer phases via selective homopolymers.

The phase behavior of strongly segregated AB diblock copolymer and selective C homopolymer blends is examined theoretically using a combination of strong stretching theory (SST) and self-consistent field theory (SCFT). The C-homopolymer is immiscible with the B-blocks but strongly attractive with the A-blocks. The effect of homopolymer content on the order-order phase transitions is analyzed. I...

متن کامل

Gyroid-Forming Diblock Copolymers Confined in Cylindrical Geometry: A Case of Extreme Makeover for Domain Morphology

The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. Abstract The self-assembly of gyroid-forming diblock copolymers confined in cylindrical geometry is studied using a combination of computer simulations and experiments. The simulations, based on a system qualitatively representative of poly(styrene-b-isoprene), are performed wi...

متن کامل

Self-assembly of 21-arm star-like diblock copolymer in bulk and under cylindrical confinement.

Phase behaviors of a 21-arm star-like diblock copolymer in bulk and under confinement were explored by using the pseudo-spectral method of a self-consistent mean field theory. An asymmetrical phase diagram in bulk was constructed by comparing the free energy of different structures. The gyroid phase was found to possess a large phase region when the inner block in the star-like diblock copolyme...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • J. Nonlinear Science

دوره 17  شماره 

صفحات  -

تاریخ انتشار 2007